Modeling the inhomogeneous response in transient<br/><br/>shearing and extensional flows of entangled/micellar solutions

Tuesday, October 13, 2009 - 2:15pm - 2:55pm
EE/CS 3-180
L. Pamela Cook (University of Delaware)
Surfactant molecules (micelles) can self-assemble in solution
into long
flexible structures known as wormlike micelles. These
structures entangle,
forming a dense network and thus exhibit viscoelastic effects,
similar to
entangled polymer melts. In contrast to 'inert' polymeric
wormlike micelles continuously break and reform leading to an
relaxation mechanism and the name 'living polymers.'
Experimental studies
show that, in shearing flows, wormlike micellar solutions
exhibit spatial
inhomogeneities, or shear bands. The VCM model, a two-species
network model was formulated to capture, in a self-consistent
manner, the
micellar breakage and reforming. This model consists of a
coupled set of
partial differential equations describing the breakage and
reforming of
two micellar species (a long species 'A' and a shorter species
‘B’) - in
addition to reptative and Rousian stress-relaxation mechanisms.
and steady-state calculations of the full inhomogeneous flow
field show
localized shear bands that grow linearly in spatial extent
across the gap
as the apparent shear rate is incremented.

This model also captures the non-monotonic variation in the
state elongational viscosity that has been reported
experimentally and
the marked differences between the response of micellar
solutions in
biaxial and uniaxial extensional flows. The non-monotonic
variation in
the extensional viscosity has important dynamical consequences
transient elongational flows; In filament stretching
designed to measure the extensional rheology of wormlike
solutions, it has been observed that the elongating filaments
suddenly rupture near the axial mid-plane at high strain rates
[Rothstein]. This newly-observed failure mechanism is not
related to
the visco-capillary thinning observed in viscous Newtonian
Results of time-dependent simulations with the model carried
out in a
slender filament formulation appropriate for elongational flows
complex fluids are presented. The simulations show that
filaments described by the VCM model exhibit a dramatic and
rupture event similar to that observed in experiments. This
instability is purely elastic in nature (i.e. it is not driven
capillarity) but arises from coupling between the evolution in
tensile stress and the number density of the entangled species.
dynamics of this localized necking are contrasted with
predictions of
other nonlinear viscoelastic models.
MSC Code: