Talk
Abstract:
Irreversible Thermodynamics and Generalized Hydrodynamics
Byung
Chan Eu
McGill University
The thermodynamic laws were originally formulated on the basis
of global macroscopic cyclic processes in large, which were
associated with engines and cycles. However, also the local
irreversible processes associated with various flow phenomena
in the context of continuum mechanics are believed to be governed
by the thermodynamic laws. In this viewpoint, for example, the
Navier-- Stokes theory of hydrodynamics can be framed within
the constraints of the thermodynamic laws of local flow processes
from the viewpoint of irreversible thermodynamics, since it
involves linear thermodynamic force--flux relations for the
constitutive equations for the stress, heat flux, and so on.
Extending this line of approach to the cases of nonlinear thermodynamic
force--flux relations, it is possible to formulate a theory
of irreversible processes in fluids and thereby frame a generalized
theory of hydrodynamics within the constraints of the local
forms of the thermodynamic laws. Such a hydrodynamic theory
is called generalized hydrodynamics. By starting from the Kelvin--Clausius
principle of the second law of thermodynamics, a local theory
of hydrodynamic processes will be formulated in such a manner
that the thermodynamic laws are satisfied irrespective of the
degree of departure from equilibrium. It will be pointed out
how the theory formulated phenomenologically can be given kinetic
theory foundations by using some kinetic equations known in
the literature. Model generalized hydrodynamic equations, which
are thermodynamically consistent, will be constructed and applied
to study the shock structure of one-dimensional flow in monatomic
gases. The theoretical results will be compared with experimental
data available in the literature. The possibility of generalizing
the theory to molecular gases will be pointed out.
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