Fine particle mass is frequently dominated by organic compounds,
a large fraction of which are secondary in origin. To date
lack of understanding of intermediates in oxidation sequences
and reaction pathways and products have represented major
sources of uncertainty (and barriers to numerical mechanism
development) but advances in both theory and experimental
techniques have advanced the science considerably in the
last few years. Hence the major challenge for organic chemistry
modeling is to reconcile the large numbers of compounds
and reaction pathways with limitations imposed by available
computing resources. Oxidation of biogenic compounds is
known to significantly contribute to the burden of organic
aerosol mass but many current generation coupled gas-aerosol
models treat all biogenic compounds within a single class
(typically represented by alpha-pinene). This paper will
assess the adequacy of this treatment using a set of explicit
mechanisms for five monoterpenes (a-pinene, b-pinene, 3-carene,
d-limonene and ocimene) which are assumed to represent monoterpene
emissions and chemistry in the atmosphere. The paper will
document differences in the mechanisms and the potential
for errors introduced by assuming that monoterpenes can
be represented individually or by a limited number of groups.
The paper will also present methods for condensing the mechanisms
for inclusion in operational fully 3-D atmospheric chemistry
models and quantifying errors introduced by mechanism reduction.